Synthesis in mesoreactors: Ru(porphyrin)CO-catalyzed aziridination of olefins under continuous flow conditions

Catal. Sci. Technol., 2016, Advance Article
DOI: 10.1039/C6CY00207B, Communication
S. Rossi, A. Puglisi, M. Benaglia, D. M. Carminati, D. Intrieri, E. Gallo
The Ru(porphyrin)CO-catalyzed addition of aryl azides to styrenes to afford N-aryl aziridines was successfully performed for the first time in mesoreactors under continuous flow conditions.

Synthesis in mesoreactors: Ru(porphyrin)CO-catalyzed aziridination of olefins under continuous flow conditions

S. Rossi,a   A. Puglisi,*a   M. Benaglia,*a   D. M. Carminati,a  D. Intrieria and   E. Galloa  
*Corresponding authors
aDipartimento di Chimica, Università degli Studi di Milano, Via Golgi 19, Milano, Italy
E-mail: alessandra.puglisi@unimi.it, maurizio.benaglia@unimi.it
Catal. Sci. Technol., 2016, Advance Article

DOI: 10.1039/C6CY00207B

The Ru(porphyrin)CO-catalyzed addition of aryl azides to styrenes to afford N-aryl aziridines was successfully performed for the first time in mesoreactors under continuous flow conditions. Mesofluidic technology allowed for a rapid screening of different parameters and a quick identification of the optimized reaction conditions.

 

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/////Synthesis in mesoreactors, Ru(porphyrin)CO-catalyzed,  aziridination of olefins,  continuous flow conditions

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